SYLLABUS

Purpose:

Soil is a three-phase system comprised of solid, liquid and gas phases distributed in a complex geometry and giving rise to large solid-liquid and liquid-gas interfacial areas. These interfaces determine, to a significant extent, the physical and biological properties of soils. The objective of this course is to familiarize students with the fundamental forces arising from interfaces and then to use that basis to explore the effects of interfaces on transport of dissolved substances and gasses, and on biological processes. The course is organized into four units. The first unit will introduce students to the theories used to quantify physical phenomena occurring at interfaces and the properties of thin films. The second unit introduces concepts of transport through saturated media and the use of breakthrough curves as diagnostic tools. The third unit is a transition from saturated media to unsaturated media and focuses on the effects of interfaces on transport. The final unit deals with transport through unsaturated media. The course is designed for graduate students or advanced undergraduate in soil science, earth sciences, physics, chemistry and engineering who desire to have a better understanding of the applications of surface chemistry and reactive transport through porous media. Students should have a background in chemistry, physics and calculus.

   
Instructors:

Dr. Lynn Dudley, Ag. Sci. 356, 797-2184, ldud@mendel.usu.edu
Dr. Dani Or, Ag. Sci. 140, 797-2637, dani@mendel.usu.edu

   
Office Hours: Lynn: MWF 1:30-3:30.
Dani: by appointment.
   
Text:

The Physical Chemistry of Surfaces, (6th ed.), Arthur Adamson

   
Grades: Grades will be based on the results of two examinations given at approximately six-week intervals. The exams will be equally weighted and each worth 25% of the final grade. Thirty percent of the final grade will be based on a class project. Students may work individually or in small groups on a project. Group projects must be cleared with the instructor. The topic must be cleared with the instructors before spring break. The projects will be presented in the class during the last two weeks of the semester. The project should be an application of the course material to the students' research problem or area of interest or the instructors will assign a model of reactive transport for the student to critically analyze and present in class. The project could be a literature review of a well-define subject, data-set analysis or a modeling exercise. The topic should be cleared with the instructors by the first midterm. The homework will not be graded, but is given as a study guide for the exams. The lecture immediately preceding each exam will review solutions to the problem sets. Additional readings may be assigned during the semester and 20% of the final grade will be determined by WebCT administered quizzes on the reading material.
   
Reading list:

Specific readings from the text, literature or supplemental material will be given at the beginning of each week. The following list of topics gives the general organization of the course.

Weeks 1 through 6 - Fundamental Aspects of Interfaces
Characterization and Thermodynamics of Interfaces; Disjoining Pressure and Thin Films; Long Range Forces (van der Waals, Lifshitz Theory, Hamaker Constant); Liquid-Gas interfaces: Surface Tension, Capillarity, Contact Angle (wetability); Electrified Interfaces; Introduction to Clay Surfaces; Other Surfaces with Constant and Variable Charge; Introduction to Adsorption Processes: Adsorption at the Solid-Gas Interface; Adsorption from Solution at the Solid-liquid Interface.

Weeks 7 through 9 - Transport through Saturated Porous Media
Issues of Scale; Units and Dimensions; Modes of Transport - Diffusion, Convection, Dispersion; The Convection Dispersion Equation (CDE); Transport at the Column and Profile Scale; Break-Through Curves (BTC) as Diagnostic Tools; Simple Analytical Solutions; Transport in Saturated Heterogeneous Systems. Nonaqueous phase entrapment.

Weeks 10 through 11 - Transport Processes and Interfaces
Retardation Coefficient, Ion Exchange, Competitive Adsorption, Biological Activity

Weeks 12 through 14 - Transport in Unsaturated Media
Interfacial Configurations in Porous Media (simple geometry); Opportunity Time - Assumption of Local Equilibrium; Boundary Layer; Student Critique of Multi-domain models: 2-site/2-region, multiple reaction, physical and chemical non-equilibrium.

   
Statement of reasonable accommodation: If a student has a disability that will likely require some accommodation by the instructor, the student must contact the instructor and document the disability through the Disability Resource Center. In cooperation with the Disability Resource Center, course material may be provided in alternative formats--large print, audio, diskette or Braille upon request.
   

 

Comments? E-mail chaves@cc.usu.edu - Page last updated on 01/16/2002 at 10:30.